Aluminium Oxide

Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula Al2O3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxidealoxite, or alundum in various forms and applications. It occurs naturally in its crystalline polymorphic phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire. Al2O3 is significant in its use to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point.

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Corundum is the most common naturally occurring crystalline form of aluminium oxide. Rubies and sapphires are gem-quality forms of corundum, which owe their characteristic colours to trace impurities. Rubies are given their characteristic deep red colour and their laser qualities by traces of chromium. Sapphires come in different colours given by various other impurities, such as iron and titanium. An extremely rare δ form occurs as the mineral deltalumite.

Chemical formula

Al2O3

Molar mass

101.960 g·mol−1

Appearance

white solid

Odor

odorless

Density

3.987 g/cm3

Melting point

2,072 °C (3,762 °F; 2,345 K)

Boiling point

2,977 °C (5,391 °F; 3,250 K)

Solubility in water

insoluble

Solubility

insoluble in all solvents

log P

0.31860

Magnetic susceptibility (χ)

−37.0×10−6 cm3/mol

Thermal conductivity

30 W·m−1·K−1

Refractive index (nD)

nω = 1.768–1.772
nε = 1.760–1.763
Birefringence 0.008

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